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【19th.Dec.】Perspectives in Molecular tectonics
日期:2019-12-19 阅读:860
题目:Perspectives in Molecular tectonics
报告人:Mir Wais Hosseini 欧洲科学院院士University of Strasbourg
时间:2019年12月19日 周四下午16:00
地点:化学B楼410会议室
邀请人:颜徐州 研究员


报告人介绍



MIR WAIS HOSSEINI, Exceptional Class Professor of chemistry at the University of Strasbourg and Senior Member of the Institut Universitaire de France, Chair of Molecular Tectonics, director of the Molecular Tectonics Laboratory. 1979-81, Graduate student (Prof. J.-M. Lehn); 1981-84, Research Assistant, CNRS, Prof. J.-M. Lehn; 1984-85, Research Associate, CNRS, Prof. J.-M. Lehn; 1985, Research Associate at Kansas University, (Prof. M. P. Mertes), Lawrence Kansas, USA; 1985-86, Postdoctoral fellow, University of California at Berkeley (Prof. K. N. Raymond), California, USA; 1986-89, Research Associate, CNRS, Prof. J.-M. Lehn; 1989, Invited Lecturer, University of Western Australia, Perth, Australia; 1990, Professor of chemistry and director of Organic Coordination Chemistry Laboratory at the University of Strasbourg, France; 1992-1997, Junior member of Institut Universitaire de France (IUF), 2004-2014senior member of Institut Universitaire de France (IUF). Chevalier de la Légion d'Honneur, Chevalier de l’Ordre des Palmes Académiques, Silver Medal of the French National Research Center (CNRS), Member of Academia Europaea; Member of The European Academy of Sciences, Arts and Humanities; Member of the European Academy of Sciences, Member of the Academy of Sciences, Letters and Arts of Alsace, Fellow of the Royal Society of Chemistry, Honarary Member of Romanian Chemical Society. 


报告介绍



Bridging the gap between microscopic (atoms and molecules) and macroscopic (materials) worlds is challenging and requires construction strategies. At the intersection of supramolecular and solid state chemistry and material sciences, we have developed an approach called molecular tectonics. This approach is based on supramolecular synthesis of crystalline materials seen as extended periodic molecular networks. Their construction by selfassembly processes results from repetitive molecular recognition events between programed tectons or building blocks. The approach is operational and versatile and allows, not only the design and construction of a variety of organic or hybrid complex architectures and core-shell crystals, but also the welding, under mild condition, of crystals into networks of crystals.


References:
M. W. HOSSEINI, "Reflexion on Molecular Tectonics", CrystEngComm., 2004, 6, 318.
*M. W. HOSSEINI, "Molecular tectonics: from simple tectons to complex molecular networks", Acc. Chem. Res., 2005, 38, 313.
*M. W. HOSSEINI, "Self-assembly and generation of complexity", Chem. Commun., Focus Article, 2005, 582.
*O. FELIX, M. W. HOSSEINI, A. DE CIAN, J. FISCHER, "Molecular Tectonics III : The Simultaneous Use of H-Bonding and Charge-Charge Interactions For the Self-Assembly of Fumaric Acid and Cyclic Bisamidinium Into One- and Two-Dimensional Molecular Networks", Angew. Chem. Int. Natl. Ed. Engl. 1997, 36, 102.
*F. HAJEK, M. W. HOSSEINI, E. GRAF, A. DE CIAN, J. FISCHER, "Molecular Tectonics VI : Self-Assembly of Convex and Concave Molecular Tectons by Inclusion Processes into Linear Molecular Array in the Solid State", Angew. Chem. Int. Natl. Ed. Engl. 1997, 36, 1760.
*C. KAES, M. W. HOSSEINI, C. E. F. RICKARD, B. W. SKELTON, A. H. WHITE, "Synthesis and Structural Analysis of a Helical Coordination Polymer Formed by the Self-assembly of a 2,2'-bipyridine based Exoditopic Macrocyclic Ligand and Silver Cations", Angew. Chem. Int. Natl. Ed. Engl., 1998, 37, 920.
*P. DECHAMBENOIT, S. FERLAY, N. KYRITSAKAS, M. W. HOSSEINI, "Molecular tectonics: control of reversible water release in porous charge-assisted H-bonded networks", J. Am. Chem. Soc., 2008, 130, 17106.
*C. ADOLF, S. FERLAY M. W. HOSSEINI, "Welding molecular crystals", J. Am. Chem. Soc. 2015, 137, 15390.
*F. ZHANG, C. R. R. ADOLF, N. ZIGON, S. FERLAY, N. KYRITSAKA, M. W. HOSSEINI "Molecular tectonics: hierarchical organization of heterobimetallic coordination networks into heterotrimetallic core-shell
crystals", Chem. Commun., 2017, 53, 3587.
*C. R. R. ADOLF, S. FERLAY, M. W. HOSSEINI “Molecular Tectonics: control of crystalline sequences”, CrystEngComm., 2018, 20, 2233.
*P. LARPENT, A. JOUAITI, N. GRUBER, M. W. HOSSEINI “Molecular tectonics: from a rigid achiral organic tecton to 3D chiral Co and Fe coordination networks”, Chem. Commun., 2019, 55, 91.


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